硫化锌英文MSDS报告（仅供参考） ****SECTION1–IdentificationoftheCompanyandtheProduct**** ProductName:ZincSulfide,Pieces,3-12mm,99.9% Manufacturer:Notavailable Address:Notavailable Phone:Notavailable Fax:Notavailable EmergencyCall:Notavailable ****SECTION2-COMPOSITION,INFORMATIONONINGREDIENTS****
+----------------+--------------------------------------+----------+-----------+
|CAS#|ChemicalName|%|EINECS#|
|----------------|--------------------------------------|----------|-----------|
|1314-98-3|ZincSulfide|99.9%|215-251-3|
+----------------+--------------------------------------+----------+-----------+
HazardSymbols:NoneListed.
RiskPhrases:NoneListed.
****SECTION3-HAZARDSIDENTIFICATION****
EMERGENCYOVERVIEW
Moisturesensitive.Thetoxicologicalpropertiesofthismaterialhave
notbeenfullyinvestigated.
PotentialHealthEffects
Eye:
Maycauseeyeirritation.
Skin:
Maycauseskinirritation.
Ingestion:
Maycauseirritationofthedigestivetract.Thetoxicological
propertiesofthissubstancehavenotbeenfullyinvestigated.
Inhalation:
Maycauserespiratorytractirritation.Thetoxicologicalproperties
ofthissubstancehavenotbeenfullyinvestigated.
Chronic:
Noinformationfound.
****SECTION4-FIRSTAIDMEASURES****
Eyes:
Flusheyeswithplentyofwaterforatleast15minutes,
occasionallyliftingtheupperandlowereyelids.Getmedicalaid.
Skin:
Getmedicalaid.Flushskinwithplentyofwaterforatleast15
minuteswhileremovingcontaminatedclothingandshoes.Washclothing
beforereuse.
Ingestion:
Getmedicalaid.DoNOTinducevomiting.Ifconsciousandalert,
rinsemouthanddrink2-4cupfulsofmilkorwater.Washmouthout
withwater.
Inhalation:
Removefromexposureandmovetofreshairimmediately.Ifnot
breathing,giveartificialrespiration.Ifbreathingisdifficult,
giveoxygen.Getmedicalaid.
NotestoPhysician:
****SECTION5-FIREFIGHTINGMEASURES****
GeneralInformation:
Asinanyfire,wearaself-containedbreathingapparatusin
pressure-demand,MSHA/NIOSH(approvedorequivalent),andfull
protectivegear.Duringafire,irritatingandhighlytoxicgases
maybegeneratedbythermaldecompositionorcombustion.
ExtinguishingMedia:
Useagentmostappropriatetoextinguishfire.DoNOTgetwater
insidecontainers.Usewaterspray,drychemical,carbondioxide,or
appropriatefoam.
****SECTION6-ACCIDENTALRELEASEMEASURES****
GeneralInformation:Useproperpersonalprotectiveequipmentasindicated
inSection8.
Spills/Leaks:
Cleanupspillsimmediately,observingprecautionsintheProtective
Equipmentsection.Sweepup,thenplaceintoasuitablecontainerfor
disposal.Avoidgeneratingdustyconditions.Provideventilation.Do
notgetwaterinsidecontainers.
****SECTION7-HANDLINGandSTORAGE****
Handling:
Washthoroughlyafterhandling.Usewithadequateventilation.
Minimizedustgenerationandaccumulation.Keepcontainertightly
closed.Avoidingestionandinhalation.Donotallowcontactwith
water.Keepfromcontactwithmoistairandsteam.
Storage:
Storeinatightlyclosedcontainer.Keepunderanitrogenblanket.
Storeinacool,dry,well-ventilatedareaawayfromincompatible
substances.Storeprotectedfrommoisture.
****SECTION8-EXPOSURECONTROLS,PERSONALPROTECTION****
EngineeringControls:
Facilitiesstoringorutilizingthismaterialshouldbeequipped
withaneyewashfacilityandasafetyshower.Useadequate
ventilationtokeepairborneconcentrationslow.
ExposureLimits
CAS#1314-98-3:
Russia:5mg/m3TWA
PersonalProtectiveEquipment
Eyes:
Wearappropriateprotectiveeyeglassesorchemical
safetygogglesasdescribedbyOSHA\'seyeandface
protectionregulationsin29CFR1910.133orEuropean
StandardEN166.
Skin:
Wearappropriateprotectiveglovestopreventskin
exposure.
Clothing:
Wearappropriateprotectiveclothingtopreventskin
exposure.
Respirators:
ArespiratoryprotectionprogramthatmeetsOSHA\'s29
CFR1910.134andANSIZ88.2requirementsorEuropean
StandardEN149mustbefollowedwheneverworkplace
conditionswarrantrespiratoruse.
****SECTION9-PHYSICALANDCHEMICALPROPERTIES****
PhysicalState:Chunks
Color:whitecrystallinechunks
Odor:Notavailable.
pH:Notavailable.
VaporPressure:Notavailable.
Viscosity:Notavailable.
BoilingPoint:Notavailable.
Freezing/MeltingPoint:1700degC
AutoignitionTemperature:Notapplicable.
FlashPoint:Notapplicable.
ExplosionLimits,lower:Notavailable.
ExplosionLimits,upper:Notavailable.
DecompositionTemperature:
Solubilityinwater:insoluble
SpecificGravity/Density:3.980
MolecularFormula:ZnS
MolecularWeight:97.43
****SECTION10-STABILITYANDREACTIVITY****
ChemicalStability:
Stableundernormaltemperaturesandpressures.
ConditionstoAvoid:
Incompatiblematerials,dustgeneration,moisture,exposuretoair,
excessheat.
IncompatibilitieswithOtherMaterials:
Moisture,strongacids,strongoxidizingagents.
HazardousDecompositionProducts:
Irritatingandtoxicfumesandgases,sulfuroxides(SOx),including
sulfuroxideandsulfurdioxide,zincoxides.
HazardousPolymerization:Hasnotbeenreported
****SECTION11-TOXICOLOGICALINFORMATION****
RTECS#:
CAS#1314-98-3:ZH5400000
LD50/LC50:
CAS#1314-98-3:Inhalation,rat:LC50=>5040mg/m3/4H;Oral,rat:
LD50=>2gm/kg;Skin,rat:LD50=>2gm/kg.
Carcinogenicity:
ZincSulfide-
NotlistedbyACGIH,IARC,orNTP.
Other:
SeeactualentryinRTECSforcompleteinformation.
****SECTION12-ECOLOGICALINFORMATION****
****SECTION13-DISPOSALCONSIDERATIONS****
Disposeofinamannerconsistentwithfederal,state,andlocalregulations.
****SECTION14-TRANSPORTINFORMATION****
IATA
Notregulatedasahazardousmaterial.
IMO
Notregulatedasahazardousmaterial.
RID/ADR
Notregulatedasahazardousmaterial.
****SECTION15-REGULATORYINFORMATION****
European/InternationalRegulations
EuropeanLabelinginAccordancewithECDirectives
HazardSymbols:Notavailable.
RiskPhrases:
SafetyPhrases:
S24/25Avoidcontactwithskinandeyes.
S28AAftercontactwithskin,washimmediatelywith
plentyofwater.
S37Wearsuitablegloves.
S45Incaseofaccidentorifyoufeelunwell,seek
medicaladviceimmediately(showthelabelwhere
possible).
WGK(WaterDanger/Protection)
CAS#1314-98-3:0
Canada
CAS#1314-98-3islistedonCanada\'sDSLList.
CAS#1314-98-3isnotlistedonCanada\'sIngredientDisclosureList.
USFEDERAL
TSCA
CAS#1314-98-3islistedontheTSCAinventory.
****SECTION16-ADDITIONALINFORMATION****
MSDSCreationDate:7/06/1999Revision#2Date:3/18/2003
Theinformationaboveisbelievedtobeaccurateandrepresentsthebest
informationcurrentlyavailabletous.However,wemakenowarrantyof
merchantabilityoranyotherwarranty,expressorimplied,withrespectto
suchinformation,andweassumenoliabilityresultingfromitsuse.Users
shouldmaketheirowninvestigationstodeterminethesuitabilityofthe
informationfortheirparticularpurposes.Innowayshallthecompanybe
liableforanyclaims,losses,ordamagesofanythirdpartyorforlost
profitsoranyspecial,indirect,incidental,consequentialorexemplary
damages,howsoeverarising,evenifthecompanyhasbeenadvisedof
thepossibilityofsuchdamages.
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